Chemical Bonding
Complete Chapter Guide: Octet Rule, Lewis Dot Structures, Ionic & Covalent Bonding, VSEPR Theory Molecular Geometries, Solved Examples & Part-B MCQs
📌 Essential Chemical Bonding Concepts
1. Octet Rule
Atoms gain, lose, or share electrons to attain 8 electrons in their outer shell (stable ns2 np6 configuration):
2. Ionic vs Covalent Bond Criterion
Electronegativity Difference (ΔEN):
3. VSEPR Repulsion Order
Repulsion between electron pairs around the central atom decreases in the order:
📐 Summary of VSEPR Molecular Geometries & Bond Angles
The Valence Shell Electron Pair Repulsion (VSEPR) Theory determines the 3D shape of covalent molecules based on the repulsion between electron pairs surrounding the central atom:
1. Linear (180°)
Example: BeCl2, CO2
Bond Pairs: 2 | Lone Pairs: 0
Central Atom: Be / C
2. Trigonal Planar (120°)
Example: BF3, BCl3
Bond Pairs: 3 | Lone Pairs: 0
Central Atom: Boron (B)
3. Tetrahedral (109°28')
Example: CH4 (Methane)
Bond Pairs: 4 | Lone Pairs: 0
Central Atom: Carbon (C)
4. Pyramidal (107°)
Example: NH3 (Ammonia)
Bond Pairs: 3 | Lone Pairs: 1
Central Atom: Nitrogen (N)
5. Bent / V-Shaped (104°30')
Example: H2O (Water)
Bond Pairs: 2 | Lone Pairs: 2
Central Atom: Oxygen (O)
Comparison: Ionic vs. Covalent Compounds
| Property | Ionic Compounds | Covalent Compounds |
|---|---|---|
| Mode of Formation | Complete transfer of electrons from metal to non-metal. | Sharing of valence electron pairs between non-metals. |
| Melting & Boiling Points | Very High (Strong electrostatic forces between ions). | Relatively Low (Weak intermolecular forces). |
| Physical State | Crystalline solids at room temperature. | Gases, liquids, or soft solids. |
| Electrical Conductivity | Conduct electricity in molten or aqueous state (not in solid). | Generally non-conductors of electricity. |
| Solubility | Soluble in polar solvents like Water; insoluble in organic solvents. | Soluble in non-polar organic solvents (Benzene, CCl4). |
📝 Short Answer Questions (2 Marks & 4 Marks)
Q1. What is the Octet Rule? Why are Noble Gases chemically inert?
- Octet Rule: Atoms of elements tend to gain, lose, or share electrons in order to acquire 8 electrons in their outermost (valence) shell to achieve chemical stability.
- Inertness of Noble Gases: Noble gases (except Helium which has a stable duplet 1s2) already possess 8 electrons in their valence shell (ns2 np6). Being completely stable, they do not react or form chemical bonds easily.
Q2. Explain the formation of an Ionic Bond in Sodium Chloride (NaCl) using electron transfer.
- Sodium (Na, Z = 11): Configuration 2, 8, 1. Loses 1 valence electron to form a stable cation:
Na → Na+ + e- - Chlorine (Cl, Z = 17): Configuration 2, 8, 7. Gains 1 electron to complete its octet and form an anion:
Cl + e- → Cl- - The strong electrostatic force of attraction between opposite ions Na+ and Cl- forms the Ionic Bond in NaCl.
Q3. Explain the formation of a Nitrogen molecule (N2) with Lewis Dot Structures and triple bond.
- Nitrogen Atom (N, Z = 7): Electronic configuration = 2, 5. Each Nitrogen atom needs 3 electrons to complete its valence octet.
- Electron Sharing: Two Nitrogen atoms share 3 pairs of valence electrons (total 6 electrons) between them.
- Bonding Result: A Triple Covalent Bond (≡) is formed between the two Nitrogen atoms:
:N ••• N: → :N ≡ N: - The molecule contains 1 triple bond and 1 lone pair on each Nitrogen atom.
🧮 VSEPR Theory Explanations & Essay Questions
Q4. Explain why Ammonia (NH3) has a bond angle of 107° and Water (H2O) has 104°30' instead of the ideal tetrahedral angle of 109°28'.
Q5. Define Chemical Bond. Differentiate between Ionic and Covalent Bonds with respect to mechanism, electron movement, and characteristic properties of compounds formed.
- Chemical Bond: The attractive force that holds atoms or ions together to form a stable chemical entity (molecule or compound).
- Ionic Bond (Electrovalent Bond):
- Formed by complete transfer of one or more valence electrons from a metal atom to a non-metal atom.
- Involves formation of positive cations and negative anions.
- Ionic compounds have high melting points, exist as crystalline solids, and conduct electricity in liquid/dissolved states.
- Covalent Bond:
- Formed by mutual sharing of electron pairs between non-metal atoms.
- Can be single (-), double (=), or triple (≡) covalent bonds depending on whether 1, 2, or 3 pairs of electrons are shared.
- Covalent compounds have lower melting points, exist as gases/liquids/soft solids, and are non-conductors of electricity.

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